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Phosphorus pentasulfide

Phosphorus pentasulfide

Phosphorus pentasulfide, is a nonmetallic inorganic compound . It is a yellow to greenish-yellow crystalline mass with an odor similar to hydrogen sulfide.



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Molecular Formula: PS5

Molecular Weight: 191.3

Phosphorus pentasulfide Properties

Melting point

286 °C

Boiling point

514°C

Density

2.09 g/mL at 25 °C(lit.)

storage temp.

Flammables area

solubility

reacts with H2O; soluble in CS2

form

Powder

color

Yellow to green

PH

1 (10g/l, H2O, 20℃)

Odor

rotten egg odor

Water Solubility

reacts

crystal system

Triclinic

Space group

P1

Stability

Hygroscopic, Moisture Sensitive

CAS DataBase Reference

  1314-80-3

 

Risk and Safety Statements

Symbol(GHS) 


GHS02,GHS07,GHS09

Signal word 

Danger

Hazard statements 

H228-H260-H302+H332-H400

Precautionary statements 

P210-P223-P231+P232-P273-P301+P312-P304+P340+P312

Hazard Codes 

F,Xn,N

Risk Statements 

11-20/22-29-50

Safety Statements 

61

RIDADR 

UN 1340 4.3/PG 2

OEB

C

OEL

TWA: 1 mg/m3, STEL: 3 mg/m3

WGK Germany 

3

RTECS 

TH4375000

13-21

Autoignition Temperature

142 °C

HazardClass 

4.3

PackingGroup 

II

HS Code 

28139000

 

Phosphorus pentasulfide Chemical Properties

Phosphorus pentasulfide, is a nonmetallic inorganic compound . It is a yellow to greenish-yellow crystalline mass with an odor similar to hydrogen sulfide. It is a dangerous fire risk and ignites by friction or in contact with water. Boiling point is 995°F (535°C) and ignition temperature is 287°F (141°C). It decomposes upon contact with water or moist air, liberating toxic and flammable hydrogen-sulfide gas. Specific gravity is 2.09, so it is heavier than water. It is toxic by inhalation, with a TLV of 1 mg/m3 of air. The four-digit UN identification number is 1340. The NFPA 704 designation is health 2, flammability 1, and reactivity 2. Primary uses are in insecticides, safety matches, ignition compounds, and sulfonation. Phosphorus pentasulfide is a greenish-gray to yellow, crystalline solid with an odor of rotten eggs. The Odor Threshold is 0.005 ppm.

Phosphorus pentasulfide Uses

In manufacture of lube oil additives and pesticides. manufacture of safety matches, ignition Compounds, and for introducing sulfur into organic Compounds. Phosphorus pentasulfide is used in the manufacture of lubricant additives, pesticides, safety matches, and flotation agents. Phosphorus pentasulfide (phosphoric sulfide, P2S5) is an insecticide. It is also an additive to oils and a component of safety matches.

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